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Abstract Extreme wet-bulb temperatures (T_w) are often used as indicators of heat stress. However, humid heat extremes are fundamentally compound events, and a givenT_wcan be generated by various combinations of temperature and humidity. Differentiating between extreme humid heat driven by temperature versus humidity is essential to identifying these extremes’ physical drivers and preparing for their distinct impacts. Here we explore the variety of combinations of temperature and humidity contributing to humid heat experienced across the globe. In addition to using traditional metrics, we derive a novel thermodynamic state variable named “stickiness.” Analogous to the oceanographic variable “spice” (which quantifies the relative contributions of temperature and salinity to a given water density), stickiness quantifies the relative contributions of temperature and specific humidity to a givenT_w. Consistent across metrics, we find that high magnitudes ofT_wtend to occur in the presence of anomalously high moisture, with temperature anomalies of secondary importance. This widespread humidity dependence is consistent with the nonlinear relationship between temperature and specific humidity as prescribed by the Clausius–Clapeyron relationship. Nonetheless, there is a range of stickiness observed at moderate-to-highT_wthresholds. Stickiness allows a more objective evaluation of spatial and temporal variability in the temperature versus humidity dependence of humid heat than traditional variables. In regions with high temporal variability in stickiness, predictive skill for humid heat-related impacts may improve by considering fluctuations in atmospheric humidity in addition to dry-bulb temperature. Significance StatementExtreme humid heat increases the risk of heat stress through its influence over humans’ ability to cool down by sweating. Understanding whether humid heat extremes are generated more due to elevated temperature or humidity is important for identifying factors that may increase local risk, preparing for associated impacts, and developing targeted adaptation measures. Here we explore combinations of temperature and humidity across the globe using traditional metrics and by deriving a new variable called “stickiness.” We find that extreme humid heat at dangerous thresholds occurs primarily due to elevated humidity, but that stickiness allows for thorough analysis of the drivers of humid heat at lower thresholds, including identification of regions prone to low- or high-stickiness extremes.